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Emerging 2D materials based on two-dimensional permethylated metal-organic networks
Project status: Ended
EN / RO
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Insight in the field of 2D materials, more specifically in the field of two-dimensional metal-organic coordination networks (2D MONs); preparation protocols; creating an appropriate library of ligands; creation of a library of permethylated 2D metal-organic networks; published scientific articles and presentations at conferences.

Articles published

  • Cazacu, M.; Racles, C.; Zaltariov, M.-F.; Dascalu, M.; Bele, A.; Tugui, C.; Bargan, A.; Stiubianu, G. From Amorphous Silicones to Si-Containing Highly Ordered Polymers: Some Romanian Contributions in the Field. Polymers 2021, 13, 1605. https://doi.org/10.3390/polym13101605
  • Damoc, M; Stoica, A.-C.; Dascalu, M.; Asandulesa, M.; Shova S.; Cazacu, M., Dual crystalline-amorphous salen-metal complexes behave like nematic droplets with AIEgens vistas, Dalton Trans., 2021, 50, 13841 - 13858. https://doi.org/10.1039/D1DT01980E
  • Stoica, A.-C.; Damoc, M.; Zaltariov, M.-F.; Racles, C.; Cazacu, M., Two-dimensional coordination polymers containing permethylated motifs - promising candidates for 2D emerging materials. Structural, behavioral and functional particularities, Reactive and Functional Polymers, 2021, 168, 105039. https://doi.org/10.1016/j.reactfunctpolym.2021.105039
  • Arauzo, A.; Bartolomé, E.; Luzón, J.; Alonso, P. J.; Vlad, A.; Cazacu, M.; Zaltariov, M.-F.; Shova, S.; Bartolomé J.; Turta, C., Slow Magnetic Relaxation in {[CoCxAPy)] 2.15 H2O}n MOF Built from Ladder-Structured 2D Layers with Dimeric SMM Rungs, Molecules, 2021, 26, 5626. https://doi.org/10.3390/molecules26185626
  • Stoica, A.-C.; Damoc, M.; Tiron, V.; Dascalu, M.; Coroaba, A.; Shova, S.; Cazacu, M., Silanol-functionalized tetranuclear copper complex and its nanoscale-heterogenization by immobilization on glass surface from solution, Journal of Molecular Liquids, 15 December 2021, 344, 117742. https://doi.org/10.1016/j.molliq.2021.117742
  • Damoc, M.; Stoica, A.-C.; Dascalu, M.; Macsim, A.-M.; Tigoianu, R. I.; Blaj, D.; Rusu, A. G.; Iacob, M.; Cazacu, M., Siloxane/Silane derivatives based on 5-amino-1,3,4-thidiazole-2-thiol and their gold complexes: interfacial phenomena based on photoluminescence, International Conference Progress in Organic and Macromolecular Compounds 28th Edition, Macro Iasi 2021, Iasi, Romania, October 7 - 9, 2021, Proceedings (Online) ISSN 2810 - 2347 ISSN - L 2810 - 2126
  • V.M. Hiiuk, S.I. Shylin, D.D. Barakhtii, D.M. Korytko, V.O. Kotsyubynsky, A. Rotaru, S. Shova, I.A. Gural’skiy, Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au), Inorganic Chemistry 2022, 61, 4, 2093–2104, https://doi.org/10.1021/acs.inorgchem.1c03302, FI: 5,436
  • R.I. Gurtovyi, S.P. Gavrish, L.V. Tsymbal, M.-O. Apostu, M. Cazacu, S. Shova, Y. D. Lampeka, 2D coordination polymers and ionic complexes of the nickel(II) and zinc(II) cyclam cations with trigonal carboxylate linkers based on triazine core. Crystal structures, supramolecular catenation and spectral characterization, Polyhedron 221 (2022) 115870,  https://doi.org/10.1016/j.poly.2022.115870, FI: 2,975.
  • M. Damoc, A.-C. Stoica, D.-A. Blaj, A.-M. Macsim, M. Dascalu, C. Cojocaru, S. Shova, M. Cazacu, Fourteen-member silacycle built by cascade reactions induced by a platinum catalyst, Journal of Molecular Structure, 1269, 2022, 133760, 0022-2860, https://doi.org/10.1016/j.molstruc.2022.133760, FI: 3,841.
  • A.-C. Stoica, M. Damoc, C. Cojocaru, A. Nicolescu, S. Shova, M. Dascalu and M. Cazacu, Some theoretical and experimental evidence for particularities of the siloxane bond, Molecules 2022, 27, https://doi.org/10.3390/molecules27238563, FI: 4,927.
  • M. Damoc, R.I. Tigoianu, A.-C. Stoica, A.-M. Macsim, M. Dascalu, S. Shova, M. Cazacu), Micellization Turned on Dual Fluorescence and Room Temperature Phosphorescence by Pseudo-ESIPT in Thiadiazole Derivatives, Journal of Physical Chemistry C, jp-2022-064557, acceptata FI: 4,177.
  • M. Damoc, A.-C. Stoica, M. Cazacu, Merging hydrophobic moieties within five-membered heterocycles. Mighty approaches toward achieving some spectacular phenomena, Scientific communications of young researchers, MacroYouth’2022, 3th Edition, Iasi, November 18, Proceedings, 11-12.
  • A.-C.Stoica, M. Damoc, S. Shova, G. Novitchi, M. Dascalu, M. Cazacu, Manganese(II) 3D Metal-Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Properties, Inorganics 2023, 11, 21, https://doi.org/10.3390/inorganics11010021, FI:2,9; Q2
  • M. Damoc, R.I. Tigoianu, A.C. Stoica, A.M. Macsim, M. Dascalu, S. Shova, M. Cazacu, Micellization Turned on Dual Fluorescence and Room Temperature Phosphorescence by Pseudo-ESIPT in Thiadiazole Derivatives, The Journal of Physical Chemistry C 2023, 127 (1), 99-109, https://doi.org/10.1021/acs.jpcc.2c07651, FI:3,7; SRI:1,51, Q2
  • M. Damoc, V. Tiron, C. Tugui, C.D. Varganici, A.C. Stoica, G. Novitchi, M. Dascalu, M. Cazacu, Ferronematic Co(II) Complex: An Active Filler for Magnetically Actuated Soft Materials, Small 2023, 2307006, https://doi.org/10.1002/smll.202307006, FI=13,3/Q1
  • Zaltariov, M.-F.; Shova, S.; Cazacu, M., S-block coordination polymers built up with silicon-containing carboxylate linkers, Progress in Organic and Macromolecular Compounds - Proceedings, ISSN 2810 - 2126 | ISSN-L 2810 - 2126; ISSN 2810 - 2347 (Online version) https://icmpp.ro/macroiasi2023/proceedings.php, pp.71-73
  • Stoica, A.C.; Dascalu, M.; Damoc, M.; Cazacu, M., Some coordination polymers with pyridine-based ligands: synthesis and structural characterization, Progress in Organic and Macromolecular Compounds - Proceedings, ISSN 2810 - 2126 | ISSN-L 2810 - 2126; ISSN 2810 - 2347 (Online version), https://icmpp.ro/macroiasi2023/proceedings.php, pp.135-137
  • Zaltariov, M.F., Metal-Organic Frameworks: Emerging Porous Materials for Energy Applications, Chapter 3 in Advances In Energy Materials- New Composites and Techniques for Future Energy Applications, Eds. I. Stoica, A.R. Abraham, A.K. Haghi, Apple Academic Press, pp. 47-77 (2024). Published October 27, 2023 by Apple Academic Press

Conference

  • Stoica, A.-C.; Damoc, M.; Stiubianu, G. T.; Cazacu, M., Permethylated two-dimensional Metal-Organic Frameworks - Promising Candidates for Emerging 2D Materials, International Conference on Advances in Functional Materials, UCLA (AAAFM-UCLA) - oral presentation online
  • Damoc, M.; Stoica, A.-C.; Dascalu, M.; Macsim, A.-M.; Tigoianu, R. I.; Blaj, D.; Rusu, A. G.; Iacob, M.; Cazacu, M., Siloxane/Silane derivatives based on 5-amino-1,3,4-thidiazole-2-thiol and their gold complexes: interfacial phenomena based on photoluminescence, International Conference Progress in Organic and Macromolecular Compounds 28th Edition, Macro Iasi 2021, Iasi, Romania, October 7 - 9, 2021 - oral presentation, Best Oral Presentation for MSc/PhD/postdoc students (Romanian International Chapter of ACS).
  • M.-F. Zaltariov, Metal-organic framework (MOFs) – alternative routes in conservation of cultural heritage, Conferința științifică internațională „Patrimoniul cultural de ieri – implicații în dezvoltarea societății durabile de mâine” ediția a V-a - 22 februarie 2022, Chișinău, oral presentation
  • M.-F. Zaltariov, M. Avadanei, C.-D. Varganici, I. Spiridon,  Silicone materials embedding lanthanum complexes. The behavior in artificial weathering conditions, Cultural heritage of yesterday – Contribution to the development of a sustainable society of tomorrow,  the VIth Edition, Iași-Chișinău, 27 – 28 September 2022, oral presentation
  • M. Damoc, R.I. Tigoianu, A.-C. Stoica, A.-M. Macsim, M. Dascalu, S. Shova, M. Cazacu, Efficient light harvesting strategies by suppressing the kasha’s rule in thiadiazole derivatives, A XXXVI-a Conferință Națională de Chimie, Călimănești-Căciulata, 4-7 octombrie 2022, oral presentation 
  • A.-C. Stoica, M. Damoc, M. Dascalu, M. Cazacu,  Coordination polymers built with 1,3-bis(cyanopropyl)tetramethyldisiloxane ligand, A XXXVI-a Conferință Națională de Chimie, Călimănești-Căciulata, 4-7 octombrie 2022, oral presentation
  • A.C. Stoica, M. Damoc, M. Dascalu, M. Cazacu, Particularități în comportarea chimică a 1,3-bis(2-minoetilaminometil)tetrametildisiloxanului, Sesiunea de Comunicari Științifice a Studenților, Masteranzilor și Doctoranzilor, ”Chimia-frontieră deschisă spre cunoaștere”, Ediția a XIII-a, Iași, 28 octombrie 2022, oral presentation
  • M. Damoc, A.-C. Stoica, M. Cazacu, Merging hydrophobic moieties within five-membered heterocycles. Mighty approaches toward achieving some spectacular phenomena, Scientific communications of young researchers, MacroYouth’2022, 3th Edition, Iasi, November 18, 2022, oral presentation
  • Mirela-Fernanda Zaltariov, Sergiu Shova, Maria Cazacu, S-block coordination polymers built up with silicon-containing carboxylate linkers, Progress in Organic and Macromolecular Compounds 29th Edition, Iasi, Romania, October 4 - 6, 2023 - communication
  • Madalin Damoc, V. Tiron, C. Tugui, Cristian-Dragos Varganici, Alexandru-Constantin Stoica, Ghenadie Novitchi, Mihaela Dascalu, Maria Cazacu, A ferronemtic Co(II) coordination compound suitable as active filler for magnetically actuated materials, Madalin Damoc, Vasile Tiron, Codrin Tugui, Progress in Organic and Macromolecular Compounds 29th Edition, Iasi, Romania, October 4 - 6, 2023 - communication Best Oral Presentation
  • Mirela-Fernanda Zaltariov, Silicon-based Metal-Organic Frameworks for Biomedical Applications: Opportunities and Challenges, The international scientific conference "Cultural heritage of yesterday - implications for the development of tomorrow's sustainable society" 7th edition. The scientific event held in the context of the International Day of Girls and Women with Activities in the Field of Science February 9-10, 2023, Chisinau - conferinta online
  • Alexandru-Constantin Stoica, Mihaela Dascalu, Madalin Damoc, Maria Cazacu, Some coordination polymers with pyridine-based ligands: synthesis and structural Characterization, Progress in Organic and Macromolecular Compounds 29th Edition, Iasi, Romania, October 4 - 6, 2023 - poster Best Young Scientist Poster Presentation
  • Damoc, M., Stoica, A.-C., Cazacu, M., Engineering Organic Heterocycles and Silacycles Through a Pt(II), Catalyst The International School on Innovations in Homogeneous and Supported Homogeneous Catalysis, 25-28 aprilie, 2023, Bucuresti, Romania - poster
  • Damoc, M., Tigoianu, R.I., Stoica, A.-C., Cazacu, M., High-Energy Intermolecular Proton Transfer Generating Multiple Emissions in Aminothiadiazole Derivatives, Thematic School Vibrational and Electronic spectroscopies applied to the study of reaction mechanisms - MECAREACT, 18-23 june, 2023, Paris, France - poster
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