COMPOUNDS, POLYMERS AND ORGANIC-INORGANIC MATERIALS WITH ADAPTIVE PROPERTIES
NewSmartSil

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Results

Significant achievements of the SmartSil team in the last five years (2019-2023)
The team's contribution in the field of silicones in recent years
I.The transition from passive, thermosetting silicones to active and thermo-/solvoplastic (recyclable) ones
Chemical modification of the polysiloxanes side groups
Tuning the electromechanical performance of silicone elastomers through the crosslinking pattern
I.1.2. Preparation of silicone composites
I.1.2. Preparation of silicone composites
I.1.3. Formulations and processing technologies
All-silicone 3D printing technology
Some performances of the electromechanical transducers built on the basis of the materials developed by the team
National/International collaborations for joint research or projects
Boron nitride (BN)-silicone composites
I.2. Smart, sustainable (self-healing and recyclable) silicones
I.2.1.Smart silicones for space applications
II. The transition from amorphous silicones to ones with a high degree of ordering
II.1.New organo-silicone compounds (proligands)
II.1.3. Synthesis of organo-functionalized silica and its post-modification for drug-delivery platforms
II.1.4. S-alkylated aminothiadiazoles. High energy photochemical processes triggered by micellization
II.1.5. Low molecular silicones (di- and cyclosiloxanes) modified with polar (carboxyl or carbonyl) groups and Copper complexes with spherical morphology formed on their basis
II.1.6. Obtaining one of the largest silacycles and elucidating the reaction mechanism through theoretical and experimental studies
II.1.7. Tetramethyldisiloxane-spaced salen type Schiff bases
II.2. Coordination compounds with ligands containing permethylated siloxane fragments
Ferronematic Co(II) Complex: An Active Filler for Magnetically Actuated Soft Materials
Dinuclear Mn(III) coordination nanostructure
Silanol-functionalized tetranuclear copper complex
II.2.2. 2D coordination compounds
II.2.2. 2D coordination compounds
2D coordination polymers with photoswitchable morphology
II.2.3. 3D coordination compounds
Promotion of articles through cover images in specialized magazines
ORGANIC -> SILICONE -> INORGANIC

Legend/Video


Video_1_ Out-of-plane actuation

Video_2_ Modular installation and process for obtaining multilayer polymer generators

Video_3_ Silicone 3D printer

Video_4_ Printed grid-shaped silicone object


Video_5_Soft silicone actuator

Video_6_Silicone stacked actuator

Video_7_Silicone-based generator

Video_8_Porous silicone with high adhesion (rose petal effect)


Video_9_Porous silicone with high adhesion (rose petal effect)

Video_10_Impact senzor

Video_11_Magnetic actuator

Video_12_Magnetic actuator


Video_13_Magnetic actuator

Video_14_Termoactuator based on silicone filled with LC containing siloxane

Video_15_DR-1 modified silicone moving freely on water upon UV irradiation

Video_16 2D coordination structure_1

Video_17 2D coordination structure_2

Description info 1

Description info 2

Performances of the 3D printing technology with silicones

(Other links: https://www.icmpp.ro/projects/l6/results; https://www.icmpp.ro/projects/l6/rezultate; https://www.smartsil.ro)